Stefano Sem, Sandra Jenatsch, Kleitos Stavrou, Andrew Danos,
Andrew P. Monkman and Beat Ruhstaller
J. Mater. Chem. C, 2022, Advance Article
Thermally-activated delayed fluorescence (TADF) compounds are promising materials used in emissive layers of organic light-emitting diodes (OLEDs). Their main benefit is that they allow the internal quantum efficiency of the OLED to reach up to 100% by converting non-radiative triplet states into radiative singlets. Besides the importance of having a high reverse intersystem-crossing rate, which governs triplet conversion, minimizing the non-radiative decay processes is also extremely important to reach high efficiency. In this study the researchers provide a new method to quantify not only the most important decay rates involved in the TADF process, but also the non-radiative decay rates of both singlet and triplet states individually from transient and steady state experimental optical data.